Photo-chemistry
نویسندگان
چکیده
منابع مشابه
“ Photo ” Chemistry Without Light ?
In the early seventies, Giuseppe Cilento (São Paulo University), Emil White (Johns Hopkins University) and Angelo Lamola (AT&T Bell Laboratories) postulated that typical photochemical reactions could occur in dark parts of living organisms if coupled to enzymatic sources of electronically excited products. Their paradoxical hypothesis of “photochemistry without light” was chemically anchored on...
متن کاملTarget Identification by Diazirine Photo-Cross-linking and Click Chemistry.
Target identification of biologically active small-molecules is often the rate-determining step in forward chemical genetics. Photo-affinity labeling (PAL) represents a useful biochemical strategy for target identification in complex protein mixtures. This unit describes the use of alkyl diazirine-based photo-affinity probes and Cu(I)-catalyzed click chemistry to covalently label and visualize ...
متن کاملChemistry and biological applications of photo-labile organic molecules.
Photo-labile molecules have been widely used not only in organic synthesis but also in biological study. The chemistry of the typical photo-labile organic molecules, including their structure, mechanism underlying their photo-lability and strategies to integrate them with biomolecules, is reviewed to illustrate the structural basis for photo-activable caged compounds. Biological applications of...
متن کاملLaboratory Photo-chemistry of Pahs: Ionization versus Fragmentation.
Interstellar Polycyclic Aromatic Hydrocarbons (PAH) are expected to be strongly processed by Vacuum Ultra-Violet (VUV) photons. Here, we report experimental studies on the ionization and fragmentation of coronene (C24H12), ovalene (C32H14) and hexa-peri-hexabenzocoronene (HBC; C42H18) cations by exposure to synchrotron radiation in the range of 8-40 eV. The results show that for small PAH catio...
متن کاملChemistry of Bacteriochlorophyll b: Identification of Some (Photo)Oxidation Products
Photoreactions o f bacteriochlorophyll b have been studied. They all arise from reactions at the A8,8' double-bond. The A7,8-isomerisation product 3 is formed under anaerobic conditions. Irradiation in the presence of oxygen leads to three products arising from an autoxidation reaction involving singlet oxygen. The structures o f two o f them (4, 5) have been established from their methylpheoph...
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ژورنال
عنوان ژورنال: Science
سال: 1915
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.41.1048.166-a